Flexible Packaging Inks:
Surface Printing & Lamination Inks

flexible packaging inks surface printing inks lamination inks

Flexible packaging is printed using both flexographic and gravure printing methods and comprises a number of different end-products. These include, but are not limited to packaging for:

  1. Confectionery products
  2. Cookies/ Biscuits
  3. Coffee
  4. Juice
  5. Food

Types of Flexible Packaging Inks

1. Surface Printing Inks

  • High gloss
  • Excellent rub resistance
  • Resistance to a number of different external elements, such as water, solvents, detergents and other materials that may come into contact with the printed surface

These type of inks uses a protective overprint varnish in order to increase the surface resistance and impart the desired C.O.F. and gloss

2. Lamination Inks

Lamination is the process of combining two or more substrates to form a tough packaging structure to hold and provide barrier protection for the contents.

Lamination can be accomplished with adhesives (adhesive lamination) or with molten plastic (extrusion lamination) that acts to adhere to the packaging films together.

Lamination inks are typically sealed inside the lamination structure so that the ink surface is not exposed to the outside, however, the inks must still exhibit excellent adhesion to the film on which they are printed and they must not interfere with the bonding of the lamination
films.

Differences between Surface Printing Inks and Lamination Inks

Surface printing inks – are typically formulated with waxes that migrate to the surface of the ink film to provide rub, scuff and other resistance properties. They must also have good gloss, particularly if they are not to be overprinted.

Lamination inks – do not have the gloss requirements of surface inks but they do require excellent bonding ability to ensure that the lamination structure isn’t compromised after manufacturing. They typically do not incorporate a lot of waxes or surface-active ingredients as these can often interfere with lamination bonding.

Common types of Flexible Packaging Substrates

  1. Biaxially oriented polypropylene (BOPP)
  2. Cast polypropylene (CPP)
  3. Polyester (treated or coated)
  4. Nylon
  5. Cellophane
  6. Polyethylene (LLDPE/HDPE)

Various Resin Types Used

The various resin types used, each with its advantage over another, in solvent-based flexible packaging inks are listed in the table below. Each type can be combined to increase overall performance.

Type Usage Pigment Wetting Adhesion Heat Resistance Gloss
Nitrocellulose Surface & Lamination inks Excellent Very Good Excellent Excellent
Polyurethane Surface & Lamination inks N/A Excellent Excellent Very Good
Alcohol-soluble Polyamide Surface inks Unsuitable Good Very Good Very Good
Hotmelt Polyamide Lamination inks Unsuitable Excellent Excellent Excellent
PVB Surface & Lamination inks Fair Good Excellent Very Good
Acrylic Surface inks Poor Good Good Very Good
Ketone Surface inks Poor Fair Fair Very Good
Cellulose Acetate Propionate (CAP) Surface & Lamination inks Fair Good Very Good Very Good

Pigments and Their Functions

Pigments are considered to be the chief constituent of ink and contribute about 50 per cent of its cost. A pigment is essentially any particulate solid – coloured, black, white or fluorescent – that alters the appearance of an object by the selective absorption and/or scattering of light.

Pigments colour the ink and provide gloss, abrasiveness and resistance to light, heat, solvents, etc.

The various pigments used in solvent-based flexible packaging inks are listed in the table below.

 

Raw Materials Usage Transparency Gloss/ Brilliance Heat Resistance Stability
Organic pigments Surface & Lamination inks 5 out of 5

Excellent

5 out of 5

Excellent

4 out of 5

Moderate

5 out of 5

Excellent

Inorganic pigments Surface & Lamination inks 3 out of 5

Fair

4.5 out of 5

Very Good

5 out of 5

Excellent

5 out of 5

Excellent

Metallic pigments (Should be non-leafing) Surface & Lamination inks 1 out of 5

Poor

5 out of 5

Excellent

4 out of 5

Moderate

5 out of 5

Excellent

Additives and Their Functions in Printing Inks

Additives play a critical role in the formulation and production of inks, helping to impart the necessary characteristics the ink needs, whether it is to run more smoothly on the press or to protect the finished product. These additives come in many forms, whether it is waxes, surfactants, defoamers or countless other products. It may not take a lot of a particular additive to improve ink, but the right ingredient can make a major difference. These include:

  1. Plasticisers – enhance the flexibility of the printed film;
  2. Wax – promotes rub resistance;
  3. Drier – catalyzes the oxidation reaction of inks that dry by oxidation;
  4. Chelating agent – increases the viscosity of the ink (aluminium chelate) and promotes adhesion (titanium chelate);
  5. Antioxidant – delays the onset of oxidation polymerization by reacting with free radicals formed during the autooxidation thus preventing them from reacting further;
  6. Surfactants – which improve wetting of either the pigment or substrate, act as stabilizing agents for pigment dispersion;
  7. Alkali – controls the viscosity/solubility of acrylic resins in water-based inks;
  8. Defoamer – which reduces the surface tension in water-based inks so that stable bubbles cannot exist;
  9. Humectants – retard premature drying; and
  10. pH modifiers (usually amine derivatives) and biocides and bacteriostats

Written by Rusty from Maha Chem Philippines

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